Allylic And Vinylic Carbocation Stability

The true structure of the conjugated allyl carbocation is a hybrid of of the two resonance structure so the positive charge is delocalized over the two terminal carbons. The rate of this step and therefore the rate of the overall substitution reaction depends on the activation energy for the process in which the bond between the carbon and the leaving group breaks and a carbocation forms. Stability of carbocation intermediates.

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